By Stuart A. Rice
This sequence offers the chemical physics box with a discussion board for serious, authoritative reviews of advances in each zone of the self-discipline. quantity 129 within the sequence maintains to file fresh advances with major, updated chapters via across the world well-known researchers.
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The mechanism of the endgroup interaction in PFPEs has not yet been clariﬁed. Previous studies have indicated that the coupling between endgroups and their binding to the solid surface is more like a hydrogen-bonding interaction  from an ab initio calculation . While other studies considered the possibilities of hydrogen transfer  and esteriﬁcation as a result of annealing , in this study, we aimed to demonstrate the short-range interaction potential functions without losing the essence of the problem.
158] used KðkÞ ¼ K 0 ( constant) to explain experimental spreading results over an amorphous carbon surface obtained from SME qualitatively. However, to describe spreading on hydrogenated and nitrogenated carbon surfaces [52,60], we introduced the concept of a screening length d for the endgroup/endgroup coupling, given by  ! k ð1:29Þ K ðkÞ ¼ K0 exp À d thus inducing a transition from surface behavior to bulk behavior. In Eqs. 29), KðkÞ > 0 and WðkÞ > 0 imply favorable endgroup interactions.
Nonetheless, we attempted to establish a correlation between ﬂy sitction (tribology) and viscosity (rheology), through the shear dominant motion of the head prior to take-off. 23, implying that there exists an underlying similarity between the rheological properties and ﬂy stiction for PFPEs. Karis and Jhon  were the ﬁrst to demonstrate the relationship between the rheological properties and tribological performance of lubricants. We believe that rheological measurements will provide complementary information to the mechanical/tribological performance of HDD lubricants.
Advances in Chemical Physics, by Stuart A. Rice